Single-component white-color photoluminescence from liquid crystal polymers: Color tuning by a combination of luminescence thermo- and mechanochromism

نویسندگان

چکیده

Pure organic luminescent materials with high efficiency in the solid state are of great importance for potential applications. Unlike blending two or three dyes, getting white-light emission from a single component is hot research topic its advantages practical Although thermo/mechanochromic smart class stimuli-responsive systems, using these to manipulate luminescence spectrum achieve full-color one rarely reported. In this work, we have designed novel liquid crystal copolymers containing different monomer ratios ethynylbiphenyl and biphenylcarbonitrile skeletons side chains. The polymers free rare precious metals exhibited thermochromism, mechanochromism, white component, state. Ethynylbiphenyl skeleton key structure as group that emits light upon heating phase. However, controlling ratio between chains essential get along good purity luminescence. thermochromism mechanochromism primarily due transition creating breaking down ?-? interactions modes molecular packing. This switches color blue (thermochromism) vice versa (mechanochromism). developed showed behavior provided simple strategy single-component

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ژورنال

عنوان ژورنال: Dyes and Pigments

سال: 2021

ISSN: ['1873-3743', '0143-7208']

DOI: https://doi.org/10.1016/j.dyepig.2021.109189